The Science of Discworld II

be transformed into heat. But the sum of the two is always the same. The Second Law states, in more precise terms (which we explain in a moment), that heat cannot be transferred from a cool body to a hotter one. And the Third Law states that there is a specific temperature below which the gas cannot go – ‘absolute zero’, which is around -273 degrees Celsius.
    The most difficult – and the most interesting – of these laws is the Second. In more detail, it involves a quantity that is again called ‘entropy’, which is usually interpreted as ‘disorder’. If the gas in a room is concentrated in one corner, for instance, this is a more ordered (that is, less disordered!) state than one in which it isdistributed uniformly throughout the room. So when the gas is uniformly distributed, its entropy is higher than when it is all in one corner. One formulation of the Second Law is that the amount of entropy in the universe always increases as time passes. Another way to say this is that the universe always becomes less ordered, or equivalently less complex, as time passes. According to this interpretation, the highly complex world of living creatures will inevitably become less complex, until the universe eventually runs out of steam and turns into a thin, lukewarm soup.
    This property gives rise to one explanation for the ‘arrow of time’, the curious fact that it is easy to scramble an egg but impossible to unscramble one. Time flows in the direction of increasing entropy. So scrambling an egg makes the egg more disordered – that is, increases its entropy – which is in accordance with the Second Law. Unscrambling the egg makes it less disordered, and decreases energy, which conflicts with the Second Law. An egg is not a gas, mind you, but thermodynamics can be extended to solids and liquids, too.
    At this point we encounter one of the big paradoxes of physics, a source of considerable confusion for a century or so. A different set of physical laws, Newton’s laws of motion, predicts that scrambling an egg and unscrambling it are equally plausible physical events. More precisely, if any dynamic behaviour that is consistent with Newton’s laws is run backwards in time, then the result is also consistent with Newton’s laws. In short, Newton’s laws are ‘time-reversible’.
    However, a thermodynamic gas is really just a mechanical system built from lots of tiny spheres. In this model, heat energy is just a special type of mechanical energy, in which the spheres vibrate but do not move en masse . So we can compare Newton’s laws with the laws of thermodynamics. The First Law of Thermodynamics is simply a restatement of energy conservation in Newtonian mechanics, so the First Law does not contradict Newton’s laws. Neither does the Third Law: absolute zero is just the temperature at which the spheres cease vibrating. The amount of vibration can never be less than zero.
    Unfortunately, the Second Law of Thermodynamics behaves very differently. It contradicts Newton’s laws. Specifically, it contradicts the property of time-reversibility. Our universe has a definite direction forits ‘arrow of time’, but a universe obeying Newton’s laws has two distinct arrows of time, one the opposite of the other. In our universe, scrambling eggs is easy and unscrambling them seems impossible. Therefore, according to Newton’s laws, in a time-reversal of our universe, unscrambling eggs is easy but scrambling them is impossible. But Newton’s laws are the same in both universes, so they cannot prescribe a definite arrow of time.
    Many suggestions have been made to resolve this discrepancy. The best mathematical one is that thermodynamics is an approximation, involving a ‘coarse-graining’ of the universe in which details on very fine scales are smeared out and ignored. In effect, the universe is divided into tiny boxes, each containing (say) several thousand gas molecules. The detailed motion inside such a box is ignored, and only the average state of its molecules is considered.
    It’s a bit like a picture on a computer screen. If you look at it from a distance, you can see cows and trees and all kinds of structure. But if you look sufficiently closely at a tree, all you see is one uniformly green square, or pixel. A real tree would still have detailed structure at this scale – leaves and twigs, say – but in